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This paper provides an in-depth exploration of the technical principles and implementation methods for exporting private keys marked as non-exportable from the Windows certificate store. It begins by analyzing the security mechanisms of non-exportable private keys, then details the core method of bypassing restrictions through memory patching technology, with a focus on explaining the working principles and usage steps of the mimikatz tool. The article also discusses alternative solutions such as ExportNotExportablePrivateKey and Jailbreak tools, highlighting their implementation differences, and provides technical integration suggestions for the .NET environment. Finally, it analyzes the risks and protective measures of these technologies from a security perspective.